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61.
V. L. Oleinik 《Journal of statistical physics》1990,59(3-4):665-678
The mathematical foundation of the tight binding approximation is given. If 0 is a negative energy level of a real potentialq, then there exists an energy band for a one-dimensional chain with period 2T of the same atoms which lies near 0. We study this band whenT tends to infinity.On leave of absence from the Department of Physics, Leningrad State University, Leningrad, USSR. 相似文献
62.
舒兰褐煤树脂组分中某些分离物的化学研究 总被引:3,自引:0,他引:3
我国褐煤资源丰富 ,分布于云南、吉林、黑龙江、山东和内蒙古等地。褐煤除作燃料和腐植肥料外 ,还应用于轻化工和机械工业 ,如从褐煤制取褐煤蜡。褐煤蜡中含有较多的树脂物质 ,影响了褐煤蜡的质量 ,因此通常褐煤蜡树脂作为废弃物脱除 ,以提高褐煤蜡的质量。褐煤蜡的化学组成为纯蜡和树脂 ,前者为高碳脂肪酸和脂肪醇的酯类、游离脂肪酸和脂肪醇 ,以及烃类物等 ;后者则以萜类为主 ,并含有甾醇、羟基酸和烃化合物[1~ 5] 。 1982年唐运千等采用红外光谱和氢核磁共振谱检定 ,褐煤树脂中含有 β 谷甾醇 ;柱层析和薄层层析检出雌二醇和雌酚酮[2 ] … 相似文献
63.
64.
The effect of CuO on the thermal behaviour of Zr/KClO4 primer mixtures was studied by thermoanalytical techniques, and the Bruceton method and its related calculation. It was found that the CuO catalytically promoted the decomposition of Zr/KClO4 primer mixtures and shifted the exothermic peak of DSC curves to lower temperatures. In addition, the Zr/KClO4 primer mixture containing CuO had a significant effect on the firing characteristics of electro-explosive devices. 相似文献
65.
66.
A. E. Raevskaya A. L. Stroyuk S. Ya. Kuchmii Yu. M. Azhnyuk V. M. Dzhagan M. Ya. Valakh 《Theoretical and Experimental Chemistry》2006,42(3):162-168
The optical characteristics of CdSe nanoparticles, produced in aqueous solutions and polymer films in the reaction of cadmium
chloride and sodium selenosulfate, were studied. The main parameters that make it possible to vary the forbidden band width
were identified. The absorption, photoluminescence, Raman, and nonstationary decolorization spectra of CdSe nanoparticles
of various sizes were analyzed. It was demonstrated that under the conditions of pulsed irradiation the CdSe nanoparticles
are capable of accumulating excess electrons and inducing redox transformations in components of the solution (oxygen, methylviologen,
and sulfite ions).
__________
Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 42, No. 3, pp. 150–155, May–June, 2006. 相似文献
67.
W 7-agarose是常用的细胞外CaM功能的拮抗剂,本实验采用荧光光谱法研究了水溶液中钙调素拮抗剂W 7-agarose与植物胞外钙调素的相互结合反应。W 7-agarose是一种将W 7-共价连接到颗粒型agarose(琼脂糖)的粒子。W 7-agarose颗粒较大且容易沉淀,静置5m in后,溶液中的荧光强度完全由游离的CaM产生。在溶液中加入W 7-agarose后,溶液中一部分CaM与其结合后沉降至荧光比色皿底部,导致溶液中CaM的荧光强度下降。由此可以确定溶液中游离CaM的浓度。根据公式lg{[Q]t(F0-F)/F0}=nlg{[Q]tF/F0} lgnK[B]t,从而计算出配位体系的结合常数和配比。研究表明:二者以摩尔比1∶1结合,其平衡常数为4.9×105。由此进一步计算了W 7-agarose对胞外钙调素的拮抗率,在拮抗剂W 7-agarose浓度达到15~20μmol/L时,拮抗率可达到90%以上,与文献报道的生物学体内实验结果一致,从分子水平上解释了W 7-agarose与CaM的结合作用。 相似文献
68.
A method is described for the rapid and automatic analysis of flexible molecular alignments using multidimensional scaling and a normalized scoring scheme. A projection scheme was devised to separate orientational and conformational effects. It is shown that the approach can be utilized for the identification of common binding orientations or to the study of differences in partioning behavior. It is suggested that the method can be employed as a novel approach exploring molecular similarity as a dynamic property, so that it includes aspects of motion (by way of mutual orientations), conformations and molecular properties. 相似文献
69.
IntroductionElectrontransferreactionsarethekeystepsinphoto synthesis ,respirationandmanyotherbiochemicalprocess es.1Cytochromeb5isaredoxproteinexistingwidelyinnature ,whichactsasanelectron carrierduringvariouselectrontransferprocessesinthebiologicalsystem .2Cytochromeb5isamembraneproteinwithmolecularweightofapproximately 16kDa ,ofwhichthehydrophobicC terminaldomainanchorscytochromeb5tothemem brane ,andthehydrophilicN terminaldomaincontainshemeprostheticgroupandexhibitsthebiologicalfunctionsof… 相似文献
70.
Grell D. Grell E. Bugnon P. Dietrich B. Lehn J.-M. 《Journal of Thermal Analysis and Calorimetry》2004,77(2):483-495
The coordination of divalent and monovalent inorganic anions to synthetic polyammonium receptors is investigated in aqueous
solution around neutral pH by titration calorimetry and NMR spectroscopy. High-affinity 1:1 complexes are formed by a pyrrole
type cryptand (1) with sulfate and phosphate, characterized by association constants of almost 107 M-1. Affinities close to 105 M-1 are found for polyazacryptands (3 and 4) exhibiting F-/Cl- selectivity. The binding affinities and the anion selectivities are mainly caused by the charges of ligands and anions, which
is discussed on the basis of simple calculations of the electrostatic contribution to the anion/receptor interactions. The
binding of all investigated anions is exothermic at 298.2 K. The contribution of the large negative ΔH values to the free
energy of anion binding of the pyrrole type ligand is partially compensated by marked negative ΔS values. These unfavorable
entropic contributions are attributed to the additional inclusion of water molecules in the anion/receptor complexes.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献